今回は分子量・式量・原子量についてしっかり把握し使いこなせることを目標に学習していく。
今日のポイント
原子量・分子量・式量のすべての単語の意味を理解する
1.分子量・式量・原子量とは？
・原子量
ご存じの通り原子一つの大きさはとてつもなく小さい。炭素原子一つの大きさは直径0.10ナノメートルと1cmの一億分の一倍と小ささがうかがえる。当然この大きさであるため原子一つの重さはとても小さくなるわけであり、私たちが普段使用するには利便性が悪い。そのため、炭素原子一つの質量を12と定めそれを基準とした相対質量を開発した。それが原子量である。これにより、原子の重さが扱いやすくなった。当然実際の重さではなくただの質量の比であるため原子量には単位がない。
・分子量
分子量は炭素を12を基準とした分子量の質量である。分子は原子の集合体なので分子量は原子量の総和で表すことができる。
・式量
イオン結合などによってできる物質など組成式で表される化合物は分子を作ることがないため分子量と呼ぶことはできない。そのため式量と呼ぶが式量の求め方は分子量と同じように組成式を形成するすべての元素の原子量の総和を求めることによって導く。化学基礎の問題を解くうえでは、ほとんど分子量と同じという認識で問題ないだろう。
2,原子の相対質量
上記の通り、原子量は炭素を12とした相対質量で求めることができるがここではそれを少し掘り下げて考えてみよう
前述のとおり原子の重さはとても小さいものである。水素の重さは約1.7×10⁻²⁴ ｇ、酸素は26.5×10⁻²⁴ ｇととても小さい値であることが確認できる。これを用いて水(H₂O)分子一個の重さを考えると
(1.7×10⁻²⁴)×2 ＋ (26.5×10⁻²⁴)×1 ＝ 29.9×10⁻²⁴ ｇ
となる。このように原子一個の値を用いて分子量を求めてもいいが計算がめんどくさいのとなにより実際のところどちらが大きいのかをイメージすることが難しい。例えば、炭素原子一個の重さは19.9×10⁻²⁴ ｇであるが、これが水素の何倍であるかというのを簡単に導ける人間は少ないと思う。そのため、原子量は炭素(C)の重さを12とした相対質量をあらかじめ用いていることによって分子量の計算を簡略化し、原子や分子の重さのイメージを簡単にしているのである
各原子量の求め方は簡単な比の計算で求めることができる。炭素一個の質量は19.926×10⁻²⁴ ｇ、水素一個の重さを1.6735×10 ⁻²⁴ ｇである。これをもとに水素の原子量をxとおいて考えると
19.926×10⁻²⁴ : 1.6375×10⁻²⁴ = 12 : x
x= (1.6375×10⁻²⁴ × 12) ÷ 19.926×10⁻²⁴
x=1.0078 となり、水素の原子量を求めることができる。
このような原子量は計算をする際は通常与えられているため暗記をする必要はない。ただ、原子量＝原子一個分の重さでないということは把握しておこう。
3,同位体の存在比
元素には同じ元素でも中性子の数の違いにより質量が異なる同位体というものが存在する。しかしながら、この同位体という存在は普通の原子のなかにはある一定の割合で存在しているにも関わらず、識別することは容易ではない。そのため、一般に用いてる原子量、これは各同位体の相対質量とその存在比で求めている。
例えば、炭素には質量数12のものと13のものが存在している。これらの存在割合は質量数12のものが98.9%、13のものが1.1%程である。これらをもとに炭素の原子量を計算すると
炭素の原子量= 12 × ( 98.9 / 100 ) + 13 × ( 1.1 / 100 ) ≒ 12.01
のように求めることができる。
原子量 = ( 同位体の相対質量 × 存在比/100 ) の総和
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